NYB Syllabus

Chemistry of solutions (202-NYB-05) Ref: Zumdahl/Zumdahl, 10 th Ed.

Chap. 11 - PROPERTIES OF SOLUTIONS

SectionSuggested problems
11.1Solution Composition13, 15, 17, 39, 41, 45
11.2 The Energies of Solution Formation* 23, 27, 51, 53
11.3 Factors Affecting Solubility 57
11.4 The Vapor Pressures of Solutions 22, 59, 61, 63, 65, 67
11.5 Boiling-Point Elevation and Freezing-Point Depression 71, 73, 75, 109
11.6 Osmotic Pressure 79, 81, 110
11.7 Colligative Properties of Electrolyte Solutions 85, 87, 93, 95
*The student is invited to review intermolecular forces (section 10.1 pp. 385 to 392)

Chap. 13 - CHEMICAL EQUILIBRIUM

SectionSuggested problems
13.1The Equilibrium Condition13
13.2 The Equilibrium Constant 25, 27, 29, 81, 82
13.3 Equilibrium Expressions Involving Pressures** 33, 35, 49
13.4 Heterogeneous Equilibria 37, 41
13.5 Applications of the Equilibrium Constant 19, 51, 55
13.6 Solving Equilibrium Problems 59, 62, 64, 85, 87
13.7 Le Châtelier’s Principle 71, 77, 92
**The student is invited to review Dalton’s law of partial pressure (section 5.5 pp. 183 to 189)

Chap. 14 - ACIDS AND BASES

SectionSuggested problems
14.1The Nature of Acids and Bases39, 40, 41
14.2 Acid Strength 43, 45, 47
14.3 The pH Scale 53
14.4 Calculating the pH of Strong Acid Solutions 57, 59, 63
14.5 Calculating the pH of Weak Acid Solutions 69, 73, 75, 77, 79, 81
14.6 Bases 85, 87, 89, 93, 99
14.7 Polyprotic Acids 111
14.8 Acid-Base Properties of Salts 113, 115, 117, 119, 125, 127, 129
14.9 The Effect of Structure on Acid-Base Properties 131, 133
14.10 Acid-Base Properties of Oxides 135

Chap. 15 - ACIDS AND BASES (buffer & titration)

SectionSuggested problems
15.1Solutions of Acids or Bases Containing a Common Ion25, 27
15.2 Buffered Solutions 35, 39, 41, 47, 123
15.3 Buffering Capacity 43, 49, 57, 59
15.4 Titrations and pH Curves 61, 63, 65, 73, 100
15.5 Acid-Base Indicators 75

Chap. 16 – SOLUBILITY AND COMPLEX ION EQUILIBRIA

SectionSuggested problems
16.1Solubility Equilibria and the Solubility Product23, 31, 37, 43, 45, 50
16.2 Precipitation and Qualitative Analysis (pp 649-653) 51, 53, 59

Chap. 12 - CHEMICAL KINETICS

SectionSuggested problems
12.1Reaction Rates25
12.2 Rate Laws: An Introduction 29
12.3 Determining the Form of the Rate Law 31, 37, 100
12.4 The Integrated Rate Law 41, 42, 51, 52, 55
12.5 Reaction Mechanisms 13, 15, 61, 63, 65, 66
12.6 A Model for Chemical Kinetics 67, 69, 73, 75
12.7 Catalysis 79, 85

Chap. 17 - CHEMICAL THERMODYNAMICS

SectionSuggested problems
6.1Nature of EnergyChap. 6: 37, 38, 41, 43, 44, 106
17.1 Spontaneous Processes and Entropy 29, 35, 36
17.2 Entropy and the Second law of Thermodynamics
17.3 The Effect of Temperature on Spontaneity 37
17.4 Free Energy 39, 41, 43, 45 to 49
17.5 Entropy Changes in Aqueous Ionic Solutions
17.6 Entropy Changes in Chemical Reactions 51
17.7 Free Energy and Chemical Reactions 57, 60, 65, 68
17.8 The Dependence of Free Energy on Pressure 71, 73
17.9 Free Energy and Equilibrium 77, 83
17.10 Free Energy and Work