Dissociation constants of some acids and bases at 25°C
(for Ka values click here)
|
arrange the compounds in alphabetical order | |
Acid | Formula | pKa1 | pKa2 | pKa3 |
Sulfuric acid | H2SO4 | very small | 1.921 | |
Oxalic acid | H2C2O4 | 1.229 | 4.194 | |
Sulfurous acid | H2SO3 | 1.77 | 7.194 | |
Phosphoric acid | H3PO4 | 2.124 | 7.206 | 12.444 |
Ferric ion | Fe(H2O)63+ | 2.398 | | |
Hydrofluoric acid | HF | 3.452 | | |
Nitrous acid | HNO2 | 3.337 | | |
Acetylsalicylic acid (aspirin) | HC9H7O4 | 3.523 | | |
Arsenic acid | H3AsO4 | 3.602 | 7.252 | 12.523 |
Formic acid | HCOOH | 3.745 | | |
Ascorbic acid | H2C6H6O6 | 4.102 | 11.796 | |
Benzoic acid | HC6H5COO | 4.19 | | |
Acetic acid | HCH3COO | 4.754 | | |
Propionic acid | HC2H5COO | 4.873 | | |
Aluminum ion | Al(H2O)43+ | 4.921 | | |
Carbonic acid | H2CO3 | 6.367 | 10.251 | |
Hydrosulfuric acid | H2S | 7 | 19 | |
Hypochlorous acid | HClO | 7.456 | | |
Hydrocyanic acid | HCN | 9.307 | | |
Zinc ion | Zn(H2O)42+ | 9.602 | | |
Phenol | HC6H5O | 9.886 | | |
Hydrogen peroxide | H2O2 | 11.62 | | |
|
Water | H2O | pKw = 14.00 | | |
|
Base | Formula | pKb1 | pKb2 | |
Calcium hydroxide | Ca(OH)2 | 2.427 | 1.398 | |
Piperidine | C5H11N | 2.879 | | |
Zinc hydroxide | Zn(OH)2 | 3.018 | | |
Diethylamine | (C2H5)2NH | 3.161 | | |
Dimethylamine | (CH3)2NH | 3.268 | | |
Triethylamine | (C2H5)3N | 3.284 | | |
Ethylamine | C2H5NH2 | 3.367 | | |
Methylamine | CH3NH2 | 3.432 | | |
Trimethylamine | (CH3)3N | 4.190 | | |
Ammonium hydroxide | NH4OH | 4.747 | | |
Ammonia | NH3 | 4.751 | | |
Codeine | C18H21O3N | 5.788 | | |
Morphine | C17H19O3N | 5.790 | | |
Nicotine | C10H14N2 | 5.979 | 10.879 | |
Hydroxylamine | NH2OH | 8.041 | | |
Isoquinoline | C9H7N | 8.602 | | |
Pyridine | C5H5N | 8.750 | | |
Quinoline | C9H7N | 9.201 | | |
Aniline | C6H5NH2 | 9.370 | | |
Caffeine | C8H10N4O2 | 10.4 | | |
Glycine or aminoacetic acid | H2NCH2COOH | 11.650 | 4.225 | |
|
Handbook of Chemistry and Physics. 64th Ed.
R. C. Weast Editor. CRC Press, Inc. Boca Raton Florida. 1983-84. D-164 to D-169 |